EPR studies of photochemical reactions of [MeCpMo(CO)3]2 with quinones
β Scribed by Minoru Hanaya; Masamoto Iwaizumi
- Book ID
- 103228182
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 818 KB
- Volume
- 417
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The absolute rate constants of the reactions F + H2CO + HF + HCO (1) and Br + HzCO + HBr f HCO (21 have been measured usmg the discharge flow reactor-EPR method Under pseudo-frrstarder conditions ( I H2CO I > I F I or I BF I), the foelowmg values were obtamed at 298 K: ICI = (6 6 f 1 1) X lo-\*' and
CF 3 O 2 CF 3 was photolyzed at 254 nm in the presence of CO in 760 torr N 2 or air at 296 K in a static reactor. In N 2 , the products CF 3 OC(O)C(O)OCF 3 and CF 3 OC(O)O 2 C(O)OCF 3 were detected by FTIR spectroscopy. In air, the only observed products were CF 2 O and CO 2 and a chain process, ini