Studies on the rate of isotopic oxygen e
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Fred F. Kashani; R. Kent Murmann
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Article
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1985
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John Wiley and Sons
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English
β 479 KB
π 1 views
The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex