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EPR studies of isotopic exchange involving adsorbed oxygen species on MgO

✍ Scribed by M. Che; B. Shelimov; J.F.J. Kibblewhite; A.J. Tench


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
385 KB
Volume
28
Category
Article
ISSN
0009-2614

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The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex