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EPR Spectroscopy of Cu(I)−NO Adsorption Complexes Formed over Cu−ZSM-5 and Cu−MCM-22 Zeolites

✍ Scribed by Umamaheswari, V.; Hartmann, Martin; Pöppl, Andreas


Book ID
127035810
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
233 KB
Volume
109
Category
Article
ISSN
0022-3654

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Electron spin resonance studies of Cu(I)
✍ V. Umamaheswari; M. Hartmann; A. Pöppl 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 465 KB

Cu(I)-NO complexes, one of the essential intermediates in the NO decomposition reaction, were formed over copper exchanged and autoreduced Cu-ZSM-5, Cu-MCM-58, Cu-ZSM-12, and Cu-L zeolites, and studied by electron spin resonance spectroscopy at X-, Q-, and W-band frequencies. The spin Hamiltonian pa