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EPR spectra of C60anions

✍ Scribed by S. S. Eaton; G. R. Eaton

Book ID
113000781
Publisher
Springer Vienna
Year
1996
Tongue
English
Weight
942 KB
Volume
11
Category
Article
ISSN
0937-9347

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Upon photo-and electrochemical in situ reduction of [ 60 ] fullerene derivatives, (n = 1, 2), C 60 [ C(COOEt) 2 ] n characteristic single-line EPR spectra are observed which are attributable to the corresponding radical anions. Monofunctionalized shows a reduction behavior similar to pristine i.e. f

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Photochemically and electrochemically reduced [60]fullerene encapsulated in ~/-cyclodextrin ([60]fullerene/~-CD) forms in aqueous solution four radical products (T, X, A, B) identified by EPR with the following g-values and peak-to-peak widths, pp: T: gT= 2.0015, ppT=0.02 roT; X: gx = 2.0012, PPx =0