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EPR of the vanadyl ion in Tutton salts at zero magnetic field

✍ Scribed by Steven J. Strach; Richard Bramley

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 511 KB
Volume: 109
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85602-x

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✦ Synopsis

EPR mcasuremcnts at zero magnetic field have provided ;Iccur;Itc mcasurcmcnts of hypcrfiic principal values for the vanadyl ion doped in a series of Tutton salts. Unlike in previous EPR determinations, 111~ in-plane anisotropy of the flyperfine tensor was found to vary only slightly from one environment IO another. The nuclear quadrupolc interaction term has also been dcrcrmincd from the zero-field spectrum and yields CI value for the nuclear quadrupole moment of 5 1 V in agreemcnt with that determined from atomic-beam mcasurcmcnts.

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