EPR of the Four-Copper-Ion Complex with Spin S = 2 in Triglycine Fluoroberylate Monocrystal

Formalism of the Rhombic Spin Hamiltonia

Formalism of the Rhombic Spin Hamiltonian with S = 2 and Its Application to EPR Spectra of Copper Aggregates in TGFB: Cu2+

✍ M. Maćkowiak; M. Kurzyński 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 598 KB

## Abstract The properties of the spin Hamiltonian for __S__ = 2 in a crystal field of rhombic symmetry are analysed up to terms with __a, b, c__ proportional to the fourth power of spin operators, and a method for the determination of constants of this Hamiltonian is proposed. By perturbation calc