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Epoxy resins based on aromatic glycidylamines. VI. Toughening of N,N,N′,N′-tetraglycidyl-4,4′-diaminodiphenylmethane by reactive additives

✍ Scribed by I. Dobáš; S. Luňák; J. Zelenka; J. Horálek; V. Špaček; S. de Petris


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
478 KB
Volume
45
Category
Article
ISSN
0021-8995

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Epoxy resins based on aromatic glycidyla
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## Abstract __N,N,N′,N′__‐tetrakis(2,3‐epoxypropyl)‐4,4′‐diaminodiphenylmethane (__N,N,N′,N′__‐tetraglycidyl‐4,4′‐diaminodiphenylmethane, TGDDM) and an intermediate of its synthesis, __N,N,N′,N′__‐tetrakis(2‐hydroxy‐3‐chloropropyl)‐4,4′‐diaminodiphenylmethane (__N,N,N′,N′__‐tetrachlorohydrin of 4,4

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## Abstract __N,N__‐bis(2,3‐epoxypropyl) aniline (__N,N__‐diglycidylaniline, DGA) and an intermediate of its synthesis, __N,N__‐bis(2‐hydroxy‐3‐chloropropyl) aniline (__N,N__‐dichlorohydrin of aniline, DCHA), were analyzed by GPC and HPLC. The main impurities were isolated by semipreparative HPLC a

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The course of intramolecular cyclization of N,N-bis ( 2-hydroxy-3-chloropropyl) aniline (DCHA) was followed by HPLC. The rate constants (at 70,85,100, and 115OC) and the Arrhenius parameters for individual reaction steps were determined. The resulting product was isolated by semipreparative HPLC and