## Abstract __N,N,N′,N′__‐tetrakis(2,3‐epoxypropyl)‐4,4′‐diaminodiphenylmethane (__N,N,N′,N′__‐tetraglycidyl‐4,4′‐diaminodiphenylmethane, TGDDM) and an intermediate of its synthesis, __N,N,N′,N′__‐tetrakis(2‐hydroxy‐3‐chloropropyl)‐4,4′‐diaminodiphenylmethane (__N,N,N′,N′__‐tetrachlorohydrin of 4,4
Epoxy resins based on aromatic glycidylamines. VI. Toughening of N,N,N′,N′-tetraglycidyl-4,4′-diaminodiphenylmethane by reactive additives
✍ Scribed by I. Dobáš; S. Luňák; J. Zelenka; J. Horálek; V. Špaček; S. de Petris
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 478 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0021-8995
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## Abstract __N,N__‐bis(2,3‐epoxypropyl) aniline (__N,N__‐diglycidylaniline, DGA) and an intermediate of its synthesis, __N,N__‐bis(2‐hydroxy‐3‐chloropropyl) aniline (__N,N__‐dichlorohydrin of aniline, DCHA), were analyzed by GPC and HPLC. The main impurities were isolated by semipreparative HPLC a
The course of intramolecular cyclization of N,N-bis ( 2-hydroxy-3-chloropropyl) aniline (DCHA) was followed by HPLC. The rate constants (at 70,85,100, and 115OC) and the Arrhenius parameters for individual reaction steps were determined. The resulting product was isolated by semipreparative HPLC and