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Epoxide Formation by Ring Closure of the Cinnamyloxy Radical

✍ Scribed by Amaudrut, Jérôme; Wiest, Olaf


Book ID
126906302
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
71 KB
Volume
2
Category
Article
ISSN
1523-7060

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Formation of some bicyclic systems by ra
✍ Athelstan L.J. Beckwith; George Phillipou; Algirdas K. Serelis 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 186 KB

The rates and stereochemistry of ring closure of the radicah (21, (Lj), Cl\_?), and (161 have been detemined and rationalised. Recently,l we suggested that 1,5-ring closures of substituted hex-5-enyl radicals and related acyclic species are stereoselective: l-or 3-substituted systems give mainly ci