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Epoxidation of Unsaturated Fatty Materials with Peracetic Acid in Glacial Acetic Acid Solution

✍ Scribed by Findley, Thomas W.; Swern, Daniel; Scanlan, John T.

Book ID
120505666
Publisher
American Chemical Society
Year
1945
Tongue
English
Weight
382 KB
Volume
67
Category
Article
ISSN
0002-7863

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In situ Formation of Peracetic Acid in I
In situ Formation of Peracetic Acid in Iron-Catalyzed Epoxidations by Hydrogen Peroxide in the Presence of Acetic Acid
✍ Megumi Fujita; Lawrence Que Jr. πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 102 KB πŸ‘ 2 views

## Abstract Iron complexes (tpa)Fe(OTf)~2~ (1) and (bpmen)Fe(OTf)~2~ (2) [tpa=tris‐(2‐pyridylmethyl)amine; bpmen=__N,Nβ€²__‐bis‐(2‐pyridylmethyl)‐__N,N′‐__dimethyl‐1,2‐ethylenediamine] were found to catalyze the __in situ__ formation of AcOOH from H~2~O~2~ and AcOH in the course of olefin oxidations.