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Epoxidation of unsaturated fatty esters in argentation chromatography

✍ Scribed by Sybil L. Chen; Robert A. Stein; James F. Mead

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
284 KB
Volume
16
Category
Article
ISSN
0009-3084

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✦ Synopsis

Absorption chromatography of unsaturated esters on silver ion-silica gel columns leads to the formation of epoxides, if solvents containing peroxides are used. With small samples of radioactive esters the epoxide is formed in proportion so large that subsequent analytical pro cedures will reveal the epoxide, to the possible confusion of the investigator. Data on the behavior of epoxides of common unsaturated fatty esters in TLC and GLC are presented.

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