Epoxidation of Styrene to Styrene Oxide: Synergism of Heteropoly Acid and Phase-Transfer Catalyst under Ishii−Venturello Mechanism

Kinetics and mechanism of the gas-phase

Kinetics and mechanism of the gas-phase oxidation of styrene to benzaldehyde, acetophenone and trans-cinnamaldehyde over a heterogeneous surface-vanadate Wacker catalyst

✍ Evert van der Heide; John Schenk; Albert W. Gerritsen; Joseph J. F. Scholten 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 379 KB

## Abstract A study has been made of the kinetics and mechanism of the oxidation of styrene over a heterogeneous vanadate‐monolayer Li~2~PdCl~4~ Wacker catalyst in the temperature range 348 K to 453 K at 0.11 MPa total pressure. The kinetics of the reaction, with respect to the dependence of the re