Epoxidation of exoxyclic glycals: A new access to glycosides of ketosugars
β Scribed by Francesco Nicotra; Luigi Panza; Giovanni Russo
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 219 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract A convenient method for the stereoselective synthesis of diasteroisomeric vinyl epoxides (β)β**2Ξ±** and (β)β**2Ξ²**, the carba analogs of Dβgalactal and Dβallalβderived vinyl epoxides **1Ξ±**and **1Ξ²**, has been elaborated starting from triβ__O__βacetylβDβglucal. The key step of this synt
A novel, highlysteremekctive intemtolectdar cycloaddition reactionof simple and enantiopure cyclicnitronw toglucose sadgaktosederived1,2-glycals offersa direct accessto a new classof pseudoaza-Cdisaecharides withisoxazoliditte shwture, potential glycosidsse itdtibiters. The synthesis of new(1+2)-lin