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Epoxidation of Bacterial Polyesters with Unsaturated Side Chains. I. Production and Epoxidation of Polyesters from 10-Undecenoic Acid

✍ Scribed by Park, Won Ho; Lenz, Robert W.; Goodwin, Steve

Book ID
126781614
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
148 KB
Volume
31
Category
Article
ISSN
0024-9297

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📜 SIMILAR VOLUMES

Epoxidation of bacterial polyesters with
Epoxidation of bacterial polyesters with unsaturated side chains. II. Rate of epoxidation and polymer properties
✍ Won Ho Park; Robert W. Lenz; Steve Goodwin 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 154 KB 👁 2 views

Poly(3-hydroxyoctanoate-co-3-hydroxy-10-undecenoate)s (PHOUs) with controlled amounts of unsaturated repeating units were epoxidized to various extents with m-chloroperbenzoic acid (MCPBA) in homogeneous solution. The epoxidation reaction was second order, with an initial rate constant of 1.1 ϫ 10 Ϫ

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The vinyl groups in the pendant substituents of a series of poly(3-hydroxyoctanoate-co-3-hydroxy-10-undecenoate)s, PHOUs, were completely converted into epoxide groups with m-chloroperbenzoic acid to produce a series of copolymers, poly(3hydroxyoctanoate-co-3-hydroxy-10,11-epoxyundecenoate)s, PHOEs

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## Abstract The production of phenoxy‐substituted poly(3‐hydroxyalkanoates) (PHA) by __Pseudomonas oleovorans__ was investigated. 11‐Phenoxyundecanoic acid was used as a single carbon source for the bacterial culture. At the maximum growth rate of the culture, the cells were isolated by centrifugat