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Epoxidation catalyzed by iron(III) and manganese(III) pyridine-2-carboxamido complexes

✍ Scribed by Li Yang; Rui-Ning Wei; Rui Li; Xiang-Ge Zhou; Jing-Lin Zuo

Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
287 KB
Volume
266
Category
Article
ISSN
1381-1169

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## Abstract The asymmetric epoxidation of unfunctionalised olefins to epoxides is realised by using manganese(III) complexes stabilised on nanocrystalline magnesium oxide in the presence (1__R__,2__R__)‐(βˆ’)‐diaminocyclohexane as a chiral ligand in good yields and up to 91 % enantiomeric excess.