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Epimerization and deuterium exchange studies in selected cis,trans-1-alkyl-2-aryl(alkyl)-3-aroylaziridines

โœ Scribed by Philip Tarburton; A. Chung; Robert C. Badger; Norman H. Cromwell


Book ID
112123705
Publisher
Journal of Heterocyclic Chemistry
Year
1976
Tongue
English
Weight
349 KB
Volume
13
Category
Article
ISSN
0022-152X

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By treatment with organocopper reagents, N-activated 2,3-cis-3-alkyl-2-vinylaziridines produced exclusively (E)-allyl amines in high yields, presumably via an anti-SN2' reaction pathway. On the other hand, under otherwise identical conditions, N-activated 2,3-trans-3-alkyl-2-vinylazaridines gave an