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Epicubenol synthase. Origin of the oxygen atom of a bacterial sesquiterpene alcohol

✍ Scribed by David E. Cane; Ning Ke

Book ID
104364933
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
116 KB
Volume
10
Category
Article
ISSN
0960-894X

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✦ Synopsis

AbstractÐIncubation of epicubenol synthase with farnesyl pyrophosphate in the presence of 11.1 atom% H 2 18 O gave epicubenol (2) in which the hydroxyl oxygen atom was shown to be derived exclusively from water, as established by GC-selected ion monitoring MS of the derived TMS-epicubenol derivative (15).

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poly[d(G-C)], 36786-90-0; poly d(G).poly d(c), 25512-84-9; poly[d(A-T)], 26966-61-0; poly d(A)\*poly d(T), 24939-09-1; poly[d(T-G)]\*poly[d(C-A)], 27732-52-1; p~ly[d(T-C)]\*p~ly[d(G-A)], 29627-66-5; p~ly[d(A-T-C)].p~ly[d-(G-A-T)], 24939-08-0; p~ly[d(T-T-G)]\*p~ly[d(C-A-A)], 27902-32-5; poly[d(T-A-C)