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Enzyme reactions in apolar solvent. 5. The effect of adjacent unsaturation on the porcine pancreatic lipase catalyzed kinetic resolution of secondary alcohols

✍ Scribed by Morgan, Brian; Oehlschlager, Allan C.; Stokes, Thomas M.

Book ID: 120658468
Publisher: American Chemical Society
Year: 1992
Tongue: English
Weight: 830 KB
Volume: 57
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00037a049

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Enzyme reactions in apolar solvents: the

Enzyme reactions in apolar solvents: the resolution of (±)-sulcatol with porcine pancreatic lipase.

✍ Thomas M. Stokes; Allan C. Oehlschlager 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 257 KB

The enantioselectivity of the transesterification of (f)-Sulcatol by porcine pancreatic lipase in ether is increased ten-fold by dehydration of the enzyme and use of 2,2,2\_trifluoroethyl laurate as the ester.