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Enzyme-mediated synthesis of new 1,3-dioxane odorants related to Floropal®

✍ Scribed by Agnese Abate; Elisabetta Brenna; Claudio Fuganti; Stefano Serra

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 176 KB
Volume: 19
Category: Article
ISSN: 0882-5734
DOI: 10.1002/ffj.1372

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✦ Synopsis

Abstract

The enzyme‐mediated synthesis of enantiomerically enriched 1,3‐dioxane odorants analogous to Floropal^®^ is here described. The complete olfactory evaluation of each sample is also reported. The addition of a single methyl group at C~5~ of the dioxane ring of Floropal^®^ modiﬁes the elicited odour sensation, still preserving a pleasant character. The substitution of the methyl group at C~6~ with just an ethyl moiety completely changes the odour proﬁle of the molecule. Even subtler are the odour differences generated by conﬁgurational variations. Copyright © 2004 John Wiley & Sons, Ltd.

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