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Enzymatic Total Synthesis of Rabelomycin, an Angucycline Group Antibiotic

✍ Scribed by Kharel, Madan Kumar; Pahari, Pallab; Lian, Hui; Rohr, Jürgen

Book ID
120373902
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
420 KB
Volume
12
Category
Article
ISSN
1523-7060

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Total Synthesis of Angucyclines, 1. – Synthesis of a Daunomycinone–Rabelomycin Hybrid
✍ Krohn, Karsten ;Ballwanz, Frank ;Baltus, Wolfgang 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 339 KB

## Abstract The synthesis of the racemic angucyclinone hybrid 3 which combines the structural features of rabelomycin (1) and daunomycinone (2) is described. Key steps are the cyclization of the bromide 6b by a Marshalk‐type reaction to yield the angular skeleton 7b, introduction of the tertiary hy