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Enzymatic synthesis of diastereospecific carbacephem intermediates using serine hydroxymethyltransferase

✍ Scribed by A J Kreuzman; J M Zock; J E Dotzlaf; J T Vicenzi; S W Queener; W K Yeh

Book ID: 110050317
Publisher: Springer-Verlag
Year: 1997
Tongue: English
Weight: 164 KB
Volume: 19
Category: Article
ISSN: 1476-5535
DOI: 10.1038/sj.jim.2900395

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## Abstract The reaction mechanism for the biomimetic synthesis of tryptophan from indole and serine in the presence of Ac~2~O in AcOH was investigated. Although the time‐course ^1^H‐NMR spectra of the reaction of 5‐methoxyindole with __N__‐acetylserine were measured in the presence of (CD~3~CO)~2~