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Enzymatic Resolution of (.+-.)-5-Acetoxy-4-aryl-(2E)-pentenoate Derivatives.

โœ Scribed by Shin Tanikawa; Machiko Ono; Hiroyuki Akita


Book ID
101983416
Publisher
John Wiley and Sons
Year
2005
Weight
22 KB
Volume
36
Category
Article
ISSN
0931-7597

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Enzymatic kinetic resolution of (ยฑ)-4-ac
โœ Antonio Cipiciani; Francesco Fringuelli; Vittorio Mancini; Oriana Piermatti; Ann ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 305 KB

The enzymatic kinetic resolution of (-+)-4-acetoxy122]paracyclophane by Candida cylindracea lipase was investigated in water and in a two-phase aqueous organic system. The (+)-(R)-4-hydroxy-and (+)-(S)-4-acetoxyl2,2l-paracyclophanes were isolated in excellent yields and high enantiomeric excesses. T