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Enzymatic Resolution, Desymmetrization, and Dynamic Kinetic Asymmetric Transformation of 1,3-Cycloalkanediols

✍ Scribed by Fransson, Ann-Britt L.; Xu, Yongmei; Leijondahl, Karin; Bäckvall, Jan-E.

Book ID
127156571
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
168 KB
Volume
71
Category
Article
ISSN
0022-3263

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✍ Jörg Pietruszka; Robert Christian Simon; Fabian Kruska; Manfred Braun 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 330 KB

## Abstract A new reaction setup for kinetic enzymatic resolution was established and is demonstrated for the case of the hydrolase‐catalysed conversion of methyl 2,3‐dihydro‐1__H__‐indene‐1‐carboxylate (**1**) in conjunction with a base‐catalysed racemisation. The system allows controlled racemisa