Deracemisation of α-Chiral Primary Amine
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Dominik Koszelewski; Dorina Clay; David Rozzell; Wolfgang Kroutil
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Article
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2009
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John Wiley and Sons
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English
⚖ 141 KB
## Abstract Racemic α‐chiral primary amines were deracemised to optically pure amines in up to >99 % conversion and >99 % __ee__ within 48 h. The deracemisation was a result of a stereoinversion of one amine enantiomer; the formal stereoinversion was achieved by a one‐pot, two‐step procedure: in th