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Enzymatic formation of TDP-3-acetamido-3,6-dideoxy hexose

✍ Scribed by Wesley A. Volk; Gilbert Ashwell


Book ID
118848282
Publisher
Elsevier Science
Year
1963
Tongue
English
Weight
243 KB
Volume
12
Category
Article
ISSN
0006-291X

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## Abstract The synthesis of 3‐deoxy‐L‐fucose (19) could not be achieved by an inversion procedure, starting from the 3‐__O__‐triflate‐activated derivatives 8 or 9, respectively. Also the Mitsunobu reaction with the 3‐OH‐unblocked sugars 6 or 7 did not lead to the desired compounds. Instead, the fo