Abstract<omplexing is studied by potentiometry in dilute thorium tetra-and dihalide solutions in molten alkali halides and some of their mixtures. The ernfof cells ThlNThX, + (1 --N)MXjMXllC, Xze, and ThlNThX,+(I-N)[N~Y+(l-N~MX)IMXtC,X,~, in which X is Cl, Br or I, Yis F, Cl or Brand M is Li, Na, K,
Entropy predictions in molten binary alkali halide mixtures
โ Scribed by R.L. Paul; H.C. Brookes
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 324 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
EWXSS entropies
for all the CONDITION anion rnolrcn binary alkali halide mixtures have been predicted, for the first time, usin:! an extension of the conformal solution theory. The wlculatcd entropies arc in good agrcernent with available experimental results.
๐ SIMILAR VOLUMES
Thermal conductivity of molten alkali halides and their mixtures with common anions is measured as a function of temperature. Use is made of the most reliable method of coaxial cylinders made of platinum, with radiation heat transfer being taken into account. It is found to vary directly with temper
Diffusion potentials at porous asbestos diaphragms separating chloride melts of different cation comnositions have been measured as functions of temperature making use of cells with chlorine electrodes. Between individual molten alkali chlorides the diffusion potentials were found to increase with t
The density and surface tension of molten alkali halides and their binary mixtures with common anions and cations are measured as a function of temperature and ionic composition. The equations are derived for their temperature dependences, with experimental error being given on a confidence level 0.