Synthesis, Structure, and Stereodynamics
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Jonathan P. H. Charmant; Guy C. Lloyd-Jones; Torren M. Peakman; Robert L. Woodwa
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Article
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1999
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John Wiley and Sons
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English
⚖ 463 KB
👁 1 views
1,8-Bis(N-benzyl-N-methylamino)naphthalene ( 2) and its hy-the free base 2 is 0.6 (± 0.07) kcal•mol -1 less stable than the dl form (∆H°= -0.64 (±0.03) kcal•mol -1 ; ∆S°= -0.18 (±0.13) drogen iodide salt [2H] + [I] -were synthesised from 1,8-diaminonaphthalene. The thermodynamic diastereomer ratios