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Entropy and Fluid−Fluid Separation in Nonadditive Hard-Sphere Mixtures: The Asymmetric Case

✍ Scribed by Saija, F.; Giaquinta, P. V.


Book ID
127216679
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
92 KB
Volume
106
Category
Article
ISSN
0022-3654

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A synthesis of the structural and dynamical phenomenology exhibited by hard spheres at equilibrium is presented, with an emphasis on the relation between entropy and multiparticle correlations. A novel criterion for the freezing of the fluid is also proposed.