✦ LIBER ✦

Entropy and Enthalpy Contributions to Solvent Effects on Phosphate Monoester Solvolysis. The Importance of Entropy Effects in the Dissociative Transition State

✍ Scribed by Hoff, Richard H.; Hengge, Alvan C.

Book ID: 127013839
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 147 KB
Volume: 63
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo981160k

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Effect of solvent and ion-pairing on the

Effect of solvent and ion-pairing on the entropy and enthalpy factors in successive reductions of dinitro compounds

✍ C.P. Andrieux; J.M. Savéant 📂 Article 📅 1974 🏛 Elsevier Science ⚖ 351 KB

Solvent and temperature effect in aldol

Solvent and temperature effect in aldol condensation between the lithium enolate of tert-butyl acetate and 2-phenyl propanal: enthalpy and entropy contribution

✍ Gianfranco Cainelli; Paola Galletti; Daria Giacomini; Paolo Orioli 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 65 KB

An analysis of nucleophilic addition of the lithium enolate of tert-butyl acetate and 2-phenyl propanal in two different solvents, such as THF and n-hexane, revealed the great importance of solvent effect in determining the stereoselectivity. In particular, temperature-dependent measurements of dias

Substituent and solvent effects on the r

Substituent and solvent effects on the rate of perester decomposition. Case for polar contributions to the transition state

✍ Engstrom, Jon P.; DuBose, John C. 📂 Article 📅 1973 🏛 American Chemical Society 🌐 English ⚖ 839 KB

Initial state and transition state contr

Initial state and transition state contributions to solvent effects on rate constants for racemisation and dissociation of the [Fe(phen)3]2+cation in DMSO-water mixtures

✍ Michael J. Blandamer; John Burgess; Stephen D. Cope; Timothy Digman 📂 Article 📅 1984 🏛 Springer 🌐 English ⚖ 413 KB

Initial state and transition state contr

Initial state and transition state contributions to solvent effects on activation enthalpies for substitution reactions of tris(1,10-phenanthroline)iron(II) in aqueous methanol

✍ Michael J. Blandamer; John Burgess; Timothy Digman; Philip P. Duce; John P. McCa 📂 Article 📅 1983 🏛 Springer 🌐 English ⚖ 553 KB

Enthalpy, Entropy, and Structural Relaxa

Enthalpy, Entropy, and Structural Relaxation Behaviors of A- and B-DNA in Their Vitrified States and the Effect of Water on the Dynamics of B-DNA

✍ Rüdisser, Simon; Hallbrucker, Andreas; Mayer, Erwin; Johari, G. P. 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 237 KB