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Entrainer Effects on Enantiodifferentiating Photocyclization of 5-Hydroxy-1,1-diphenylpentene in Near-Critical and Supercritical Carbon Dioxide

✍ Scribed by Nishiyama, Yasuhiro; Wada, Takehiko; Kakiuchi, Kiyomi; Inoue, Yoshihisa


Book ID
125454884
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
282 KB
Volume
77
Category
Article
ISSN
0022-3263

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## Abstract Rhodium‐catalyzed hydroformylation of 1,5‐hexadiene to dialdehydes was investigated in compressed CO~2~ and in toluene using different fluorinated phosphane compounds as ligands at a temperature of 60 Β°C. Product yields depend greatly on the ligand used and, of the ligands examined, tri