The transition temperature of \(\mathrm{YBa}_{2} \mathrm{Cu}_{4} \mathrm{O}_{8}(124)\) is increased by about \(10 \mathrm{~K}\) by doping with calcium, whereas Ca substitution in \(\mathrm{Y}_{2} \mathrm{Ba}_{4} \mathrm{Cu}_{7} \mathrm{O}_{14+x}\) (247) has no effect on \(T_{\mathrm{c}}\). X-ray str
Enthalpy of formation of Y2Ba4Cu7O14.916
โ Scribed by A.S. Monayenkova; A.A. Popova; V.V. Kuzmenko; J. Karpinski; K. Conder
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 120 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-9614
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โฆ Synopsis
standard molar enthalpy of formation of Y Ba Cu O at T s 298.15 K has 2 4 7 14.916 0 ลฝ . been determined by solution calorimetry to be: โฌ H Y Ba Cu O , cr, 298.15 K s f m 2 4 7 14.916 . y1 ลฝ . y 5465.7 " 7 kJ mol . During the experiment the molar enthalpies of reaction of the Y Ba Cu O high-temperature superconductor and metallic yttrium with 1.07 N HCl 2 4 7 14.916 have been measured in a hermetic rotating calorimeter equipped with an isothermal jacket. แฎ
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The new bulk, melt-textured grown composite Nd,,,Y,~,Ba,Cu,O,-, , which also forms large single crystals, has the standard high-T, 123 orthorhombic structure when oxygenated and a very high critical current density in a magnetic field of 0.5 T. Both of these results were not anticipated, as the Nd a
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