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Enthalpies of Hydrogen-Bonds in α-Helical Peptides. An ONIOM DFT/AM1 Study

✍ Scribed by Wieczorek, Robert; Dannenberg, J. J.

Book ID
120886720
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
64 KB
Volume
127
Category
Article
ISSN
0002-7863

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Recently, Presta and Rose proposed that a necessary condition for helix formation is the presence of residues at the N- and C-termini (called NTBs and CTBs) whose side chains can form hydrogen bonds with the initial four amides and the last four carbonyls of the helix, which otherwise lack intraheli