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Enthalpies of Formation of Hexaethylethane, Octamethylhexane, and Tri- tert -butylmethane. Extremely Strained Hydrocarbons †

✍ Scribed by Verevkin, Sergey P.; Nölke, Margot; Beckhaus, Hans-Dieter; Rüchardt, Christoph


Book ID
127229772
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
147 KB
Volume
62
Category
Article
ISSN
0022-3263

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Tris (methylidene)-cyclopropane (“[3]Rad
✍ Thomas Bally; Helmut Baumgärtel; Ulrich Büchler; Edwin Haselbach; Wolfgang Lohr; 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 713 KB

## Abstract The enthalpy of formation of tris(methylidene)‐cyclopropane (“[3]radialene”, **1**) has been determined as Δ__H__ = 396 ± 12 kJ mol^−1^ from three fragmentation reactions of its molecular ion **1**^+^ formed from **1** by photoionisation using synchrotron radiation. Comparative electron