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Enthalpies of formation of five crystalline dialkyldithiocarbamate copper(II) complexes The mean CuS bond-dissociation enthalpies

✍ Scribed by Manuel A.V. Ribeiro da Silva; Ana M.M.V. Reis


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
380 KB
Volume
21
Category
Article
ISSN
0021-9614

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Standard enthalpies of formation of crys
✍ Manuel A.V. Ribeiro da Silva; Ana M.M.V. Reis; Rita I.M.C.P. Faria 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 329 KB

The standard (p°= 0.1 MPa) enthalpies of formation of crystalline dimethylammoniumdimethyldithiocarbamate and of the dimethyldithiocarbamate complexes of Ni(II) and Cu(II) were determined, at the temperature 298.15 K, by solution-reaction calorimetry. The enthalpy of ''decomposition'' of the dimethy