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Enthalpies of Formation of Dibenzo- p -dioxin and Polychlorinated Dibenzo- p -dioxins Calculated by Density Functional Theory

✍ Scribed by Dorofeeva, Olga V.; Yungman, Vladimir S.


Book ID
120734859
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
215 KB
Volume
107
Category
Article
ISSN
1089-5639

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Experimental determination of the enthal
✍ S.M. Pimenova; S.V. Melkhanova; V.P. Kolesov; P.I. Demyanov; A.N. Fedotov; V.P. πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 63 KB

The standard molar enthalpy of combustion of dibenzo-p-dioxin (DD) was measured at T = 298.15 K by static-bomb combustion calorimetry: c H o m (cr) = -(5723.8 Β± 1.4) kJ β€’ mol -1 . The standard molar enthalpy of sublimation of this compound was measured by microcalorimetry: g cr H o m = (91.45 Β± 0.76