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Enthalpies of formation of bicyclo[3.3.1]non-2-ene, bicyclo[3.2.2]non-6-ene, and bicyclo[4.2.1]non-3-ene

✍ Scribed by R Jochems; H Dekker; C Mosselman; G Somsen

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
320 KB
Volume
15
Category
Article
ISSN
0021-9614

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond