Enthalpies of formation of azomethane, azoethane, and methyl-azoethane
โ Scribed by Frederick D. Rossini
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 321 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0021-9614
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๐ SIMILAR VOLUMES
The thermal decomposition of azoethane (AE) was studied by detailed product analysis in the temperature and pressure intervals 508-598 K and 2.7-13.3 kPa. Besides the hydrocarbon products, three characteristic and quantitatively important nitrogen-containing compounds were also determined: ethyl-2-b
## Abstract The thermal decompositions of azoethane and azoisopropane were studied in a large excess of ethylene in the temperature interval of 523โ623 K. It was demonstrated that under such conditions, the bulk of the alkyl radicals react with ethylene. Via measurements on the consumption of the a
The azoethane-sensitized thermal reaction of isobutene has been studied at 526-565 K. The initial concentrations of azoethane and isobutene were in the ranges of 1.40-10.5 X and 6.78-26.6 X mol/dm3, respectively. From the initial rates of formation of ethane and 2-methylpentane the heat of formatio
## Abstract The very lowโpressure (VLPP) technique was used to study the pyrolysis of azoethane (AE), azoisopropane (AIP), and 2,2โฒโazoisobutane (AIB). The low pressure rate constants were related to the highโpressure Arrhenius parameters by means of the RRKM theory. This procedure in itself does n
## Abstract The photochemistry of azoโ__n__โpropane is investigated at 366 nm up to 1 atm pressure, and over a range of temperature from 50 to 190ยฐC. Some additional experiments with azoethane at room temperature and azoisopropane at 180 and 190ยฐC are also reported. From a consideration of the pres