ent-(8S,10R)-15,16-Epoxy-19-norcleroda-4,11,13(16),14-tetraene-18,6(R):20,12-diolactone (isocrotocaudin)
โ Scribed by Said, Ikram M. ;Noor, Ainal F. A. ;Syah, Yana M. ;Latif, Jalifah ;Ngah, Nurziana ;Yamin, Bohari M.
- Book ID
- 104483747
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 197 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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โฆ Synopsis
The title compound, C 19 H 18 O 5 , is a diastereoisomer of crotocaudin, both being isolated from the plants of genus Croton. In isocrotocaudin, the furan moiety makes a dihedral angle with the adjacent lactone of 13.53 (17) . The cyclohexyl ring of the diterpene moiety adopts a chair confirmation. The weak intermolecular C-Hร ร รO hydrogen bonds link the molecules into linear chains along the c axis.
๐ SIMILAR VOLUMES
The title compound, C~22~H~28~O~8~, was prepared from the natural diterpenoid macrocalyxin J by two steps. It is built up from five fused rings: three six-membered rings and two five-membered rings. Two molecules are present in the asymmetric unit; both independent molecules have the same absolute c
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