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Enormously extended π-electronic conjugation system of dimeric octaethylporphyrin transmitted with anthracene

✍ Scribed by Kempe, Hideto; Kuroda, Natsuki; Yoshino, Junro; Hayashi, Naoto; Higuchi, Hiroyuki


Book ID
127146740
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
643 KB
Volume
55
Category
Article
ISSN
0040-4039

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Orientational isomers of the diacetylene-group connected dihexybithiophene (DHBTh) derivatives have been synthesized, in which the different octaethylporphyrin (OEP(M); M=Ni or Pd) rings are attached at the ends. Reflecting the unsymmetrical structural feature, the peculiar electronic properties of