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Enol acetylation of methyl 12-oxopodocarp-13-en-19-oate and methyl 12-oxopodocarp-8(14)en-19-oate

โœ Scribed by Bell, R. A.; Gravestock, M. B.


Book ID
126305193
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
478 KB
Volume
37
Category
Article
ISSN
0022-3263

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Pinacol rearrangement of the title group of compounds has been investigated and the structures of the adducts elucidated. Three different A-ring carbonylated compounds were obtained, two of which (2 and 4) remained with a six-member ring as in the starting material 1, and the third one (3) with a cy