Neighboring Group Participation in the Methanolysis of a Vicinal Diepoxide. -The stereochemistry of the TCNE-catalyzed methanolysis of title compounds (I) and (VII) and the influence of neighboring 3β-hydroxy group participation on the structure of the products are studied. -(HANSON,
Enhancement of neighboring group participation in the 2-norbornyl cation
✍ Scribed by C.F. Wilcox Jr.; B. Brungardt
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 291 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The solvolysis rates of a series of nitrile-substituted 2norbornyl tosylates are presented along with a semi-quantitative analysis of the rates.
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