Enhancement of hydrogen adsorption by alkali-metal cation doping of metal-organic framework-5
β Scribed by Chun-Lin Chu; Jiann-Ruey Chen; Tsung-Yu Lee
- Book ID
- 113650050
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 821 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0360-3199
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## Abstract Hydrogen storage: Simple organic molecular systems (C~__n__~H~__n__~, __n__=4, 5, 6, 8) are proposed for hydrogen storage purposes based on the concept of aromaticity. The adsorption of hydrogen is attributed to pronounced charge transfer from the sodium atom (green, see picture) to the
## Abstract __Interaction between adsorbed hydrogen and the coordinatively unsaturated Mg^2+^ and Co^2+^ cationic centres in MgβMOFβ74 and CoβMOFβ74, respectively, was studied by means of variableβtemperature infrared (VTIR) spectroscopy. Perturbation of the H~2~ molecule by the cationic adsorbing