Enhancement of 2D INADEQUATE Spectra by Means of Singular-Value Decomposition
✍ Scribed by Jörg Lambert
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 89 KB
- Volume
- 123
- Category
- Article
- ISSN
- 1064-1858
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📜 SIMILAR VOLUMES
A novel sensitivity-enhancement procedure is introduced for 2D NMR data matrices. It is based on the separation of the signal-and-noise subspaces by means of singular-value decomposition of the experimental 2D array. Although no theoretical limitation exists for a general application of the method,
A possible new application for the "singular value decompositionÏ (SVD) method is described. With the help of SVD, the isotropic NMR shifts of paramagnetic metallorganic compounds of the type (where Cp = g5-Cp 3 Ln AE B cyclopentadienyl, B = neutral base and Ln = lanthanoid) were quantitatively int