Enhanced α-CH Acidity and Reactivity of Lewis Acid–Base Complexes in the Gas Phase

✍ Scribed by Jianhua Ren; Dr. Derek B. Workman; Prof. Robert R. Squires

• Publisher: John Wiley and Sons
• Year: 1997
• Tongue: English
• Weight: 363 KB
• Volume: 36
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.199722301

✦ Synopsis

graphite-monochromated Mo,, radiation (E. = 0.7107 A). The structure was solved by direct methods (SIR92). The full-matrix least-squares refinement (teXsan package, Molecular Structure Cop.) was based on F to minimize the quantityXw(/F,I -IF,l)' with M' = l/a2(F). Non-hydrogen atomswererefined anisotropically ; hydrogen atoms were included as constant contributions to the structure factors and were not refined. The refinement converged at R , = 0.0612 and R , = 0.0650. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100113. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CBZlEZ, UK