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Enhanced stereoselectivity in aqueous intramolecular hetero Diels-Alder cycloaddition of chiral acylnitroso compounds

✍ Scribed by Masaichi Naruse; Sakae Aoyagi; Chihiro Kibayashi

Book ID: 104215614
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 310 KB
Volume: 35
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)75847-3

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✦ Synopsis

In an aqueous medium, intramolecular hetero Die&Alder cycloadditions of the chiral acylnitroso compounds, generated from the chiral hydroxamic acids by in situ periodate oxidation, shows a pronounced enhancement of the trans selectivity compared with the results obtained by employing nonaqueous conditions.

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