Enhanced ferroelectric properties of Ce-substituted BiFeO3 thin films on LaNiO3/Si substrates prepared by sol–gel process

✍ Scribed by Xiuzhang Wang; Hongri Liu; Bowu Yan

• Publisher: Elsevier Science
• Year: 2009
• Tongue: English
• Weight: 677 KB
• Volume: 29
• Category: Article
• ISSN: 0955-2219
• DOI: 10.1016/j.jeurceramsoc.2008.08.016

✦ Synopsis

The effects of Ce substitution on the structural and electrical properties of multiferroic BiFeO 3 thin films grown on LaNiO 3 /Si(1 0 0) substrates by a sol-gel process have been reported. X-ray diffraction data confirmed the substitutions of Ce into the Bi site with the elimination of all secondary phases under a substitution ratio x = 15%. The dielectric constants of the films increased from 90 to ∼260 below 100 kHz with 5% molar Ce substitution and the films showed enhanced dielectric behavior. We observed a substantial increase in the remnant polarization (P r ) with Ce substitution and obtained a maximum value of ∼71 C/cm 2 by 5% molar Ce incorporation. The leakage current behavior at room temperature of the films was studied and it was found that the leakage current density decreased from 10 -6 to 10 -8 A/cm 2 for 5% molar Ce-substituted films under a field 150 kV/cm. The reduction of dc leakage current of Ce-substituted films is explained on the basis of relative phase stability and improved microstructure of the material.