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Enhanced Electron-Transfer Properties of Cofacial Porphyrin Dimers through π–π Interactions

✍ Scribed by Atsuro Takai; Claude P. Gros; Jean-Michel Barbe; Roger Guilard; Shunichi Fukuzumi

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
110 KB
Volume
15
Category
Article
ISSN
0947-6539

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Enhanced Electron-Transfer Properties of
Enhanced Electron-Transfer Properties of Cofacial Porphyrin Dimers through π–π Interactions
✍ Atsuro Takai; Claude P. Gros; Jean-Michel Barbe; Roger Guilard; Shunichi Fukuzum 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 583 KB

## Abstract **π–π assisted**: Photoinduced electron transfer from cofacial porphyrin dimers to electron acceptors is prominently accelerated, whereas the back electron transfer is decelerated, relative to the corresponding porphyrin monomer (see figure).magnified image The radical cation of zinc t