Rates of cydobutene i~merisation induced by excilation or the 6-O =C-H strelching overtone al 16603 cm-' have been measured as a funcrion of the pressure of lhe bath gases He. Ar. CO,, CH,, SF6 and cyclobutene These data have been used LO compare energy transfer paramelers obtained from au approxima
โฆ LIBER โฆ
Energy transfer studies from excited cyclobutane chemically activated by nuclear recoil reaction
โ Scribed by N.S. Nogar; J.K. Dewey; Leonard D. Spicer
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 561 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Relative vibrational energy trznsfcr efficiencies are determined for cyclobutanc-t chemically activated to an average cncr~y of 5 eV by recoil tritium rcplaccment reaction. The pressure and composition dependence of the stabilizationdecomposition ratio indicates relative efficiencies of 1.00, 1.05, and 0.32 for cC,Ha, CF,, and Ne bath _eases.
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Energy transfer parameters from studies
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1985
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โ 611 KB