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Energy transfer in collisions of highly vibrationally excited tetrahedral molecules

โœ Scribed by M.B. Grinchak; A.A. Levitsky; L.S. Polak; S.Ya. Umanskii

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
433 KB
Volume
88
Category
Article
ISSN
0301-0104

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๐Ÿ“œ SIMILAR VOLUMES

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Collisional energy transfer in highly vibrationally excited molecules: A very low-pressure pyrolysis study of acetyl chloride
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The average downward energy transfer ((A Ed,,,)) is obtained for highly vibrationally excited acetyl chloride with Ne and C,H, bath gases at ca. 870 K. Data are obtained by the technique of very low-pressure pyrolysis (VLPP). Fitting these data by solution of the appropriate reaction-diffusion integ

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Values for (AEduwn), the average downward energy transferred from the reactant to the bath gas upon collision, have been obtained for highly vibrationally excited undeuterated and per-deuterated isopropyl bromide with the bath gases Ne, Xe, C,H,, and C,D,, a t ca. 870 K. The technique of pressure-de