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Energy Transfer Between a Cationic-Conjugated Poly(fluorene-co-phenylene) and Thiazole Orange for DNA Hybridization Detection Involving G-Rich Sequences

✍ Scribed by Bin Liu; Guillermo C. Bazan


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
178 KB
Volume
28
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Efficient energy transfer between a cationic poly(fluorene‐co‐phenylene) and thiazole orange mediated by a G‐rich oligonucleotide provided sensitized TO emission over 25 000‐fold more intense than that from free TO. Higher energy transfer efficiency to ssDNA/TO relative to dsDNA/TO leads to an improved sensitivity and selectivity in G‐rich DNA hybridization detection as compared to the direct use of TO as the signal reporter. The signal amplification provided by conjugated polymers is useful to amplify the response from other TO‐based detection protocols.

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