Energy transfer and primary product ion excitation in He+/CO2 and H2+/CO2 charge-transfer collisions
β Scribed by J.E. Parker; R.G. Milner; A.M. Robertson
- Book ID
- 107771562
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 1016 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0020-7381
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π SIMILAR VOLUMES
Intramolecular vibration-vibration energy transfer cross sections have beer. calculated for COz (0001) + H2,!Dz -+ COz(ll'0) + Hz/Dz,+ C02(10Β°0) + Hz/D\*, and-C02(20Β°0) + Hz/D2 based on the mechanism that the energy mismatch is transferred to the translational motion. For CO2 + Hz. the calculated cr
Classical trajectory calculations for the rotational excitation'of CO and Hz by collision &ith He have been carried out and compared to the accurate qu&~m mechanics1 cfculations of other workers The grecment is rasonably encourngig, although some irther&t limitations of this strictly classical appro
The relative populations of vibrational levels in the A 2nu state of CO; were derived from measured band intensities of the CO; A 2Qr -+ X 2"g emission system excited by charge transfer collisions of 100-5000 eV Hz and He+ ions with COa. At relative laboratory velocities above 4 X 10' cm/set the vib